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TECHNICAL
INFORMATION
Red Line Water WetterŪ is
designed to provide improved metal wetting and excellent corrosion
inhibition when added to plain water or a glycol coolant. The most poorly
maintained system in an automobile is usually the cooling system.
Maintenance is quite simple and only required once each year, but most
vehicle owners never routinely change the coolant or replenish the
corrosion inhibitors which are required for trouble-free operation. Proper
cooling system maintenance is very critical for most modern engines which
utilize more aluminum. Aluminum has a very high corrosion potential, even
higher than zinc, which is very widely used as a sacrificial anode. The
only property which enables aluminum to be used in a cooling system is
that it will form protective films under the proper conditions which will
prevent the uncontrolled corrosive attack of acids or bases. Poor aluminum
corrosion inhibition will cause the dissolution of aluminum at the heat
rejection surfaces, weakening the cooling system walls and water pump
casing and weakening the head gasket mating surfaces. These corrosion
products will then form deposits on the lower temperature surfaces such as
in radiator tubes which have very poor heat transfer properties, causing a
significant reduction in the cooling ability of the entire system. Red
Line Water WetterŪ will provide the proper corrosion inhibition for all
cooling system metals, including aluminum, cast iron, steel, copper,
brass, and lead.
Water has twice the heat transfer capability when compared to 50% glycol
antifreeze/coolant in water. Most passenger automobiles have a cooling
system designed to reject sufficient heat under normal operating
conditions using a 50/50 glycol solution in water. However, in racing
applications, the use of water and Water WetterŪ will enable the use of
smaller radiator systems, which means less frontal drag, and it will also
reduce cylinder head temperatures, even when compared to water alone,
which means more spark advance may be used to improve engine torque.
BENEFIT
SUMMARY
- Doubles the wetting
ability of water
- Improves heat transfer
- Reduces cylinder head
temperatures
- May allow more spark
advance for increased torque
- Reduces rust, corrosion
and electrolysis of all metals
- Provides long term
corrosion protection
- Cleans and lubricates
water pump seals
- Prevents foaming
- Reduces cavitation
corrosion
- Complexes with hard water
to reduce scale
COOLING SYSTEM REQUIREMENTS
The conventional spark ignition
gasoline engine is not a very efficient powerplant. A considerable amount
of the available fuel energy must be rejected from the metal combustion
chamber parts by the coolant and dispersed to the atmosphere through the
radiator. This heat rejection is necessary in order to prevent thermal
fatigue of the pistons, cylinder walls, and the cylinder head. Another
problem is that the combustion chamber must be cooled enough to prevent
pre-ignition and detonation. The higher the combustion chamber
temperatures, the higher the octane number required to prevent
pre-ignition and detonation. Since the octane of the available fuel is
limited, increasing temperatures in the combustion chamber require
retarding the spark timing which reduces the peak torque available. Higher
inlet temperatures also reduce the density of the fuel/air mixture,
reducing available torque further. For these reasons reducing the flow of
heat to the coolant usually reduces the efficiency of the engine. Figure 1
shows a typical heat balance diagram for a spark ignition engine. This
diagram demonstrates that the coolant in an automobile engine must absorb
and reject through the radiator 2 to 3 times the amount of energy which is
converted to brake power.
THERMAL PROPERTIES

Water has amazingly superior
heat transfer properties compared to virtually any other liquid cooling
medium - far superior to glycol-based coolants. As shown in Table 1, water
has almost 2.5 times greater thermal conductivity compared to glycol
coolants. Mixtures of glycol and water have nearly proportional
improvement due to the addition of water. Most heat is transferred in a
cooling system by convection from hot metal to a cooler liquid as in the
engine block or from a hot liquid to cooler metal surfaces, as in the
radiator. The convection coefficient of liquids in a tube is a complicated
relationship between the thermal conductivity, viscosity of the liquid,
and the tube diameter which determines the amount of turbulent flow. Since
50/50 glycol solution has about 4 times the viscosity and only 70% of the
thermal conductivity of water, the thermal convection coefficient for a
50/50 glycol solution is approximately 50% of the coefficient for water.
Water in the cooling system is capable of transferring twice as much heat
out of the same system as compared to a 50/50 glycol coolant and water
solution. In order for a 50/50 glycol mixture to reject as much heat as
water (amount of heat rejected is independent of the coolant), the
temperature differentials at the heat transfer surface must be twice as
great, which means higher cylinder head temperatures.
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TABLE
1
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Thermal
Properties of Cooling System Materials
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Material
|
Density
g/cm3
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Thermal
Conductivity
Watt/m · °C
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Thermal
Convection
Watt/m · °C
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Heat
Capacity
cal/g · °C
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Heat of
Vaporization
cal/g
|
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Water
|
1.000
|
0.60
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1829
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1.000
|
539
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Glycol
|
1.114
|
0.25
|
------
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0.573
|
226
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50/50
|
1.059
|
0.41
|
897
|
0.836
|
374
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Aluminum
|
2.70
|
155
|
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0.225
|
|
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Cast
Iron
|
7.25
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58 0
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|
.119
|
|
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Copper
|
8.93
|
384
|
|
0.093
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|
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Brass
|
8.40
|
113
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0.091
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Ceramics
|
|
1 - 10
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|
|
|
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Air
|
.0013
|
.026
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|
0.240
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HEAT TRANSFER
Red Line Water WetterŪ can
reduce cooling system temperatures compared to glycol solutions and even
plain water. Water has excellent heat transfer properties in its liquid
state, but very high surface tension makes it difficult to release water
vapor from the metal surface. Under heavy load conditions, much of the
heat in the cylinder head is transferred by localized boiling at hot
spots, even though the bulk of the cooling solution is below the boiling
point. Red Line's unique Water WetterŪ reduces the surface tension of
water by a factor of two, which means that much smaller vapor bubbles will
be formed. Vapor bubbles on the metal surface create an insulating layer
which impedes heat transfer. Releasing these vapor bubbles from the metal
surface can improve the heat transfer properties in this localized boiling
region by as much as 15% as shown in Figure 2. This figure demonstrates
the removal of heat from an aluminum bar at 304°F by quenching the bar in
different coolants at 214°F under 15 psi pressure. Compare the time
required to reduce the temperature of the aluminum to 250°F, or the
boiling point of water at 15 psi. Water WetterŪ required 3.2 seconds,
water alone 3.7 sec, 50/50 glycol in water required 10.2 sec, and 100%
glycol required 21 sec. Water alone required 15% longer, 50/50 glycol 220%
longer, and 100% glycol required 550% longer.
DYNO TEST
RESULTS
Dynamometer tests performed by
Malcolm Garrett Racing Engines showed significant improvements in coolant
temperatures using Water Wetter These tests were performed with a
Chevrolet 350 V-8 with a cast iron block and aluminum cylinder heads. The
thermostat temperature was 160°F. The engine operated at 7200 rpm for
three hours and the stabilized cooling system temperature was recorded and
tabulated below:

These
numbers are similar to the temperatures recorded in track use and
heavy-duty street use.
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Performance
Properties of Coolants
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Cooling System
Fluid
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Stabilized
Temperature
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50% Glycol/ 50% Water
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228°F
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50/50 with Water
Wetter
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220°F
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Water
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220°F
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Water with Water
Wetter
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202°F
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COOLANT EFFECTS ON PERFORMANCE
Under moderate load conditions,
each percent glycol raises cylinder head temperatures by 1°F. 50% glycol
raises head temperatures by 45°F. This increase in temperature will raise
the octane required for trace knock levels by typically 3.5 octane
numbers. A car equipped with a knock sensor will retard the timing to
compensate for the increase in octane requirement by approximately 5°,
which will reduce the maximum brake torque by about 2.1%. Racing vehicles
not equipped with knock sensors can advance timing for increased torque.
BOILING
POINT ELEVATION
Red Line Water WetterŪ does
not significantly increase the boiling point of water; however, increasing
pressure will raise the boiling point. The boiling point of water treated
with Red Line using a 15 psi cap is 250°F compared to 265°F at 15 psi
for 50% glycol. Increasing the pressure by 50% to 23 psi will increase the
boiling point of water to 265°F. Because of the doubling of the ability
of the radiator to transfer heat, boilover using Red Line treated water is
not a problem as long as the engine is circulating coolant through the
head and the fan is circulating air. Sudden shutdown after very hard
driving may cause boilover.
| SAE
880266 |
Water
+
Red Line
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50%
Glycol
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70%
Glycol
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Increase
in Cylinder
Head Temperature |
Baseline
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+45°F
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+65°F
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Increase
in Octane
(RON) Requirement |
Baseline
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+3.5
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+5.0
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Change in
Spark Timing
for Trace Knock |
Baseline
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-5.2°
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-7.5°
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| Change in
Torque |
Baseline
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-2.1%
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-3.1%
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FREEZING
POINT DEPRESSION
Red Line Water WetterŪ does
not significantly reduce the freezing point of water. If the vehicle will
see freezing temperatures, an antifreeze must be used. Water expands
approximately 9% upon freezing which can cause severe engine damage. Even
in summertime, the use of air-conditioning can blow freezing air through
the heater and cause freezing of the heater core unless approximately 20%
antifreeze is used.
CORROSION PROTECTION
Modern automotive engines now
use aluminum for heads, radiators, water pump housings, and nearly all
hose fittings. These engines require significantly greater corrosion
protection than their cast iron counterparts of the past. Aluminum is such
an electro-active metal that it requires an impenetrable corrosion
inhibitor film to prevent rapid corrosion. Acid neutralization capability
is very important. Coolant which has been left in a cooling system for
several years has probably become acidic from the oxidation of the glycol
to acids. Also, keeping the glycol concentration in the cooling system
below 50% will help stability.
Red Line also provides excellent protection from cavitation erosion in the
water pump and cylinder head. Localized boiling in the cylinder head forms
vapor bubbles which collapse when they come in contact with cooler
liquids. This collapse creates tremendous shock waves which removes the
inhibitor film from the aluminum surface and can cause catastrophic
erosion of the aluminum if the inhibitor does not reform the film quickly.
Another problem created by cavitation erosion is the deposition of the
removed aluminum as a salt with poor heat transfer properties in the lower
temperature radiator tubes. Red Line prevents this corrosion through
effective film formation and smaller vapor bubble formation, which has a
less violent collapse. Foam control is equally important since entrained
air will cause cavitation erosion due to the collapse of foam bubbles. Red
Line provides excellent control of foam with water alone and glycol
solutions.
Most coolants additives on the market provide only protection for iron and
perhaps moderate protection for aluminum. The milky soluble oil types can
actually impede heat transfer by wetting the metal surface with oil and
this oil can swell and soften rubber coolant hoses. Table 3 shows the many
tests which the Red Line formula will satisfy and how it compares to a
standard antifreeze.
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TABLE
3
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Comparison of Corrosion Inhibition
Properties
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PROPERTY
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RED LINE
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SPEC
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COOLANT A
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pH
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8.6
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7.5 - 11
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9.8
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Boiling
Point @ 15 psig
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250°F
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265°F (50%)
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Freezing
Point
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31°F
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-35°F (50%)
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-35°F
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Foaming
Height, ml
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75
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150
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50
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Color
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Pink
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Green
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Ash,
%
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0.5
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5, max.
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1
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Surface
Tension @ 100°C,
Dynes/cm2
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28.3
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58.9 (water)
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ASTM D4340 Heat Transfer
Corrosion Test, Aluminum
Weight loss, mg/cm2/wk
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0.21
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1 max.
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0.45
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ASTM D1384 Corrosion,
Weight loss, mg/specimen
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Copper
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1
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10 max.
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5
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Solder
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6
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30
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7
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Brass
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2
|
10
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5
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Steel
|
1
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10
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6
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Cast
Iron
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0
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10
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3
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Aluminum
|
16
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30
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30
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SLIPPERINESS OF COOLANTS
Red Line Water WetterŪ does
not alter the frictional property of tire rubber and water on a pavement
surface. The chart below shows the static and dynamic friction of pavement
wetted with different coolant types. Higher friction indicates less
slipperiness. The dynamic friction indicates the increase in slipping
which occurs after the tire begins to break loose. Water and water with
Water WetterŪ reduce the friction relative to dry pavement about 50%, but
it is much less than the reduction in friction caused by ethylene glycol
and even more slippery is propylene glycol.

USE
DIRECTIONS
One 12 ounce bottle treats
12-16 quarts of water or a 50% ethylene or propylene glycol solution. In
smaller cooling systems, use 4-5 caps per quart. Add directly through the
cooling system fill cap into the radiator or into the overflow tank. Do
not open a cooling system while hot. For best protection for aluminum,
replenish or replace every 15,000 miles. The anti-scaling ingredients in
Red Line Water Wetter allow its use with ordinary tap water. However,
using with distilled or deionized water will accomplish some scale removal
in the cylinder head area. For maximum temperature reductions use the most
water and the least antifreeze possible to prevent freezing in your
climate. Even in summertime the use of air-conditioning can blow freezing
air through the heater and cause freezing of the heater core unless
approximately 20% antifreeze is used. Red Line Water Wetter is available
in 12 ounce containers.
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